Electron capture induced dissociation of water embedded nucleotide anions
نویسندگان
چکیده
منابع مشابه
Dissociative electron attachment to hydrated single DNA strands.
The present experiments concern electron interactions with a film of short single strands of DNA covered by 3 monolayers of water, which corresponds to 5.25 water molecules per nucleotide. We report on the desorption of H{-}, O{-}, OH{-} from this target induced by 3-20 eV electrons. Below 15 eV, these anions emanate principally from a new type of dissociative core-excited transient anions form...
متن کاملNegative-ion electron capture dissociation: radical-driven fragmentation of charge-increased gaseous peptide anions.
The generation of gaseous polyanions with a Coulomb barrier has attracted attention as exemplified by previous studies of fullerene dianions. However, this phenomenon has not been reported for biological anions. By contrast, electron attachment to multiply charged peptide and protein cations has seen a surge of interest due to the high utility for tandem mass spectrometry (MS/MS). Electron capt...
متن کاملToward a general mechanism of electron capture dissociation.
The effects of positive charge on the properties of ammonium and amide radicals were investigated by ab initio and density functional theory calculations with the goal of elucidating the energetics of electron capture dissociation (ECD) of multiply charged peptide ions. The electronic properties of the amide group in N-methylacetamide (NMA) are greatly affected by the presence of a remote charg...
متن کاملInteractions of low-energy electrons with the FEBID precursor chromium hexacarbonyl (Cr(CO)6)
Interactions of low-energy electrons with the FEBID precursor Cr(CO)6 have been investigated in a crossed electron-molecular beam setup coupled with a double focusing mass spectrometer with reverse geometry. Dissociative electron attachment leads to the formation of a series of anions by the loss of CO ligand units. The bare chromium anion is formed by electron capture at an electron energy of ...
متن کاملReactions of polypeptide ions with electrons in the gas phase.
Reactions of electrons in the energy range below 70 eV with polypeptide cations and anions are reviewed, as well as their applications for the structural analysis of polypeptides. At very low energies (</= 0.1 eV), the major outcome is electron-capture dissociation (ECD) of S-S and backbone N-C(alpha) bonds, leading to c' and z. fragments. ECD is useful in sequencing and characterization of pos...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2009